Bobovnik, Rajko

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  • Bobovnik, Rajko (2)
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Selective laser melting and sintering technique of the cobalt-chromium dental alloy

Stamenković, Dejan; Obradović-Đuričić, Kosovka; Rudolf, Rebeka; Bobovnik, Rajko; Stamenković, Dragoslav

(Srpsko lekarsko društvo, Beograd, 2019)

TY  - JOUR
AU  - Stamenković, Dejan
AU  - Obradović-Đuričić, Kosovka
AU  - Rudolf, Rebeka
AU  - Bobovnik, Rajko
AU  - Stamenković, Dragoslav
PY  - 2019
UR  - https://smile.stomf.bg.ac.rs/handle/123456789/2472
AB  - Introduction/Objective the objective of this paper is to describe the microstructure and mechanical properties of sintered Co-Cr alloy and to emphasize its advantages and disadvantages with respect to the microstructure and mechanical properties of cast Co-Cr alloy. Methods Base Co-Cr alloy, EOSint M EOS Co-Cr SP2 (EOS GmbH, Munch, Germany), was used for the purpose of this research as the base material for sintering metal structures of metal-ceramic restorations. Metal sintering was conducted by using EOSint M 280 device of German origin in a stream of neutral gas - argon. After that, the alloy was heated over a period of 20 minutes at the temperature of 800°C. The chemical composition of the alloy was determined by energy dispersive spectroscopy. Microstructure of the tested alloy samples was examined under an optical metallographic and scanning electron microscope. Physical and mechanical properties were measured in a universal testing machine. The samples were prepared according to the standard ISO 527-1:1993. Results Chemical composition of the sintered Co-Cr alloy, determined by applying energy dispersive spectroscopy, indicated the same qualitative but different quantitative composition compared to cast Co-Cr alloys. The microstructure of the sintered Co-Cr alloy is lamellar in nature, with two dominant phases: ξ-Co and/or ξ-Cr (fcc - face-centered cubic) and γ-Co (hcp - hexagonal close-packed). Mechanical properties of the Co-Cr alloy obtained by applying selective laser melting technology compared to the cast Co-Cr alloy are superior or approximately the same. Conclusion Selective laser melting of the Co-Cr alloy is a good example of new technologies based on digitization. Together with other digitized procedures, this technology is an introduction to a new era in dentistry popularly called Dentistry 4.0. The advantages of the selective laser melting technology with respect to the conventional technology of casting Co-Cr alloy metal structures are precise metal structure fitting and eco-friendly technology.
AB  - Uvod/Cilj Cilj rada je opisati mikrostrukturu i mehaničke karakteristike sinterovane legure Co-Cr i istaći njene prednosti i mane u odnosu na mikrostrukturu i mehaničke karakteristike livene legure Co-Cr. Metode U istraživanju je korišćena bazna legura Co-Cr, Eosint M EOS Co-Cr SP2 (EOS GmbH, Minhen, Nemačka) za sinterovanje metalnih konstrukcija metalokeramičkih nadoknada. Sinterovanje metala je obavljeno na aparatu EOSint M 280 u struji neutralnog gasa argona. Nakon toga legura je žarena 20 minuta na temperaturi od 800° C. Hemijski sastav legure određivan je energodisperzivnom spektroskopijom. Mikrostruktura ispitivanih uzoraka legure posmatrana je na optičkom metalografskom i elektronskom skenirajućem mikroskopu. Fizičko-mehaničke karakteristike merene su na univerzalnoj kidalici. Uzorci su pripremani prema standardu ISO 527-1:1993. Rezultati Hemijski sastav uzoraka sinterovane legure CoCr pokazao je isti kvalitativan ali različit kvantitativan sastav u odnosu na legure Co-Cr za livenje. Mikrostruktura sinterovane legure Co-Cr je lamelarne prirode, u kojoj dominiraju dve faze: e-Co i/ili e-Cr (fcc - face-centred cubic) i g-Co (hcp - hexagonal close-packed). U poređenju sa livenom legurom Co-Cr, mehaničke karakteristike sinterovane legure Co-Cr su bolje ili približno iste. Zaključak Selektivno lasersko topljenje legure Co-Cr je dobar primer novih tehnologija zasnovanih na digitalizaciji. Zajedno sa drugim digitalizovanim procedurama koje prethode, ova tehnologija je predvorje novoj eri u stomatologiji, popularno nazvanoj Dentistry 4.0. Prednosti tehnologije selektivnog laserskog topljenja u odnosu na tehnologiju konvencionalnog livenja metalnih konstrukcija od legure Co-Cr su preciznost naleganja metalne konstrukcije i čista tehnologija.
PB  - Srpsko lekarsko društvo, Beograd
T2  - Srpski arhiv za celokupno lekarstvo
T1  - Selective laser melting and sintering technique of the cobalt-chromium dental alloy
T1  - Selektivno lasersko topljenje i sinterovanje dentalne legure kobalt-hrom
VL  - 147
IS  - 11-12
SP  - 664
EP  - 669
DO  - 10.2298/SARH190706112S
ER  - 
@article{
author = "Stamenković, Dejan and Obradović-Đuričić, Kosovka and Rudolf, Rebeka and Bobovnik, Rajko and Stamenković, Dragoslav",
year = "2019",
abstract = "Introduction/Objective the objective of this paper is to describe the microstructure and mechanical properties of sintered Co-Cr alloy and to emphasize its advantages and disadvantages with respect to the microstructure and mechanical properties of cast Co-Cr alloy. Methods Base Co-Cr alloy, EOSint M EOS Co-Cr SP2 (EOS GmbH, Munch, Germany), was used for the purpose of this research as the base material for sintering metal structures of metal-ceramic restorations. Metal sintering was conducted by using EOSint M 280 device of German origin in a stream of neutral gas - argon. After that, the alloy was heated over a period of 20 minutes at the temperature of 800°C. The chemical composition of the alloy was determined by energy dispersive spectroscopy. Microstructure of the tested alloy samples was examined under an optical metallographic and scanning electron microscope. Physical and mechanical properties were measured in a universal testing machine. The samples were prepared according to the standard ISO 527-1:1993. Results Chemical composition of the sintered Co-Cr alloy, determined by applying energy dispersive spectroscopy, indicated the same qualitative but different quantitative composition compared to cast Co-Cr alloys. The microstructure of the sintered Co-Cr alloy is lamellar in nature, with two dominant phases: ξ-Co and/or ξ-Cr (fcc - face-centered cubic) and γ-Co (hcp - hexagonal close-packed). Mechanical properties of the Co-Cr alloy obtained by applying selective laser melting technology compared to the cast Co-Cr alloy are superior or approximately the same. Conclusion Selective laser melting of the Co-Cr alloy is a good example of new technologies based on digitization. Together with other digitized procedures, this technology is an introduction to a new era in dentistry popularly called Dentistry 4.0. The advantages of the selective laser melting technology with respect to the conventional technology of casting Co-Cr alloy metal structures are precise metal structure fitting and eco-friendly technology., Uvod/Cilj Cilj rada je opisati mikrostrukturu i mehaničke karakteristike sinterovane legure Co-Cr i istaći njene prednosti i mane u odnosu na mikrostrukturu i mehaničke karakteristike livene legure Co-Cr. Metode U istraživanju je korišćena bazna legura Co-Cr, Eosint M EOS Co-Cr SP2 (EOS GmbH, Minhen, Nemačka) za sinterovanje metalnih konstrukcija metalokeramičkih nadoknada. Sinterovanje metala je obavljeno na aparatu EOSint M 280 u struji neutralnog gasa argona. Nakon toga legura je žarena 20 minuta na temperaturi od 800° C. Hemijski sastav legure određivan je energodisperzivnom spektroskopijom. Mikrostruktura ispitivanih uzoraka legure posmatrana je na optičkom metalografskom i elektronskom skenirajućem mikroskopu. Fizičko-mehaničke karakteristike merene su na univerzalnoj kidalici. Uzorci su pripremani prema standardu ISO 527-1:1993. Rezultati Hemijski sastav uzoraka sinterovane legure CoCr pokazao je isti kvalitativan ali različit kvantitativan sastav u odnosu na legure Co-Cr za livenje. Mikrostruktura sinterovane legure Co-Cr je lamelarne prirode, u kojoj dominiraju dve faze: e-Co i/ili e-Cr (fcc - face-centred cubic) i g-Co (hcp - hexagonal close-packed). U poređenju sa livenom legurom Co-Cr, mehaničke karakteristike sinterovane legure Co-Cr su bolje ili približno iste. Zaključak Selektivno lasersko topljenje legure Co-Cr je dobar primer novih tehnologija zasnovanih na digitalizaciji. Zajedno sa drugim digitalizovanim procedurama koje prethode, ova tehnologija je predvorje novoj eri u stomatologiji, popularno nazvanoj Dentistry 4.0. Prednosti tehnologije selektivnog laserskog topljenja u odnosu na tehnologiju konvencionalnog livenja metalnih konstrukcija od legure Co-Cr su preciznost naleganja metalne konstrukcije i čista tehnologija.",
publisher = "Srpsko lekarsko društvo, Beograd",
journal = "Srpski arhiv za celokupno lekarstvo",
title = "Selective laser melting and sintering technique of the cobalt-chromium dental alloy, Selektivno lasersko topljenje i sinterovanje dentalne legure kobalt-hrom",
volume = "147",
number = "11-12",
pages = "664-669",
doi = "10.2298/SARH190706112S"
}
Stamenković, D., Obradović-Đuričić, K., Rudolf, R., Bobovnik, R.,& Stamenković, D.. (2019). Selective laser melting and sintering technique of the cobalt-chromium dental alloy. in Srpski arhiv za celokupno lekarstvo
Srpsko lekarsko društvo, Beograd., 147(11-12), 664-669.
https://doi.org/10.2298/SARH190706112S
Stamenković D, Obradović-Đuričić K, Rudolf R, Bobovnik R, Stamenković D. Selective laser melting and sintering technique of the cobalt-chromium dental alloy. in Srpski arhiv za celokupno lekarstvo. 2019;147(11-12):664-669.
doi:10.2298/SARH190706112S .
Stamenković, Dejan, Obradović-Đuričić, Kosovka, Rudolf, Rebeka, Bobovnik, Rajko, Stamenković, Dragoslav, "Selective laser melting and sintering technique of the cobalt-chromium dental alloy" in Srpski arhiv za celokupno lekarstvo, 147, no. 11-12 (2019):664-669,
https://doi.org/10.2298/SARH190706112S . .
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Synthesis of PMMA/ZNO nanoparticles composite used for resin teeth

Popović, Danica; Bobovnik, Rajko; Bolka, Silvester; Vukadinović, Miroslav; Lazić, Vojkan; Rudolf, Rebeka

(Inst Za Kovinske Materiale I In Tehnologie, Ljubjana, 2017)

TY  - JOUR
AU  - Popović, Danica
AU  - Bobovnik, Rajko
AU  - Bolka, Silvester
AU  - Vukadinović, Miroslav
AU  - Lazić, Vojkan
AU  - Rudolf, Rebeka
PY  - 2017
UR  - https://smile.stomf.bg.ac.rs/handle/123456789/2210
AB  - Wear resistance is one of the most important physical properties of the artificial teeth used in acrylic dentures. The goal of this research was to synthesize a new composite material made of matrix Poly-(methyl methacrylate)-PMMA with different percentages (2 % and 3 % of volume fractions) of zinc-oxide nanoparticles (ZnO NPs) as reinforcing elements, to improve its mechanical properties. The dynamic mechanical behaviour of this composite was studied through the DMA method in comparison to the pure PMMA supported by the characterization of their microstructures. Then the wear resistance was analysed on the samples, which were prepared in the form of teeth. In this context their vertical height loss was measured after 100,000 chewing cycles on a chewing simulator, before and after the artificial thermal ageing. Investigations showed that the PMMA/ZnO NP composites dampened the vibrations better than the pure PMMA, which could be assigned to the homogenous distribution of ZnO NPs in the PMMA matrix. It was found that the mean vertical height loss for the pure PMMA teeth was significantly higher (more than 4 times) compared to composite teeth made with ZnO NPs. Introducing the thermal artificial ageing led to the finding that there was no effect on the height loss by the composite material with 3 % of volume fractions of ZnO NPs. Based on this it was concluded that PMMA/ZnO NPs composites showed improved in-vitro wear resistance compared to acrylic-resin denture teeth, so this new composite material should be preferred when occlusal stability is considered to be of high priority.
PB  - Inst Za Kovinske Materiale I In Tehnologie, Ljubjana
T2  - Materiali in Tehnologije
T1  - Synthesis of PMMA/ZNO nanoparticles composite used for resin teeth
VL  - 51
IS  - 5
SP  - 871
EP  - 878
DO  - 10.17222/mit.2017.025
ER  - 
@article{
author = "Popović, Danica and Bobovnik, Rajko and Bolka, Silvester and Vukadinović, Miroslav and Lazić, Vojkan and Rudolf, Rebeka",
year = "2017",
abstract = "Wear resistance is one of the most important physical properties of the artificial teeth used in acrylic dentures. The goal of this research was to synthesize a new composite material made of matrix Poly-(methyl methacrylate)-PMMA with different percentages (2 % and 3 % of volume fractions) of zinc-oxide nanoparticles (ZnO NPs) as reinforcing elements, to improve its mechanical properties. The dynamic mechanical behaviour of this composite was studied through the DMA method in comparison to the pure PMMA supported by the characterization of their microstructures. Then the wear resistance was analysed on the samples, which were prepared in the form of teeth. In this context their vertical height loss was measured after 100,000 chewing cycles on a chewing simulator, before and after the artificial thermal ageing. Investigations showed that the PMMA/ZnO NP composites dampened the vibrations better than the pure PMMA, which could be assigned to the homogenous distribution of ZnO NPs in the PMMA matrix. It was found that the mean vertical height loss for the pure PMMA teeth was significantly higher (more than 4 times) compared to composite teeth made with ZnO NPs. Introducing the thermal artificial ageing led to the finding that there was no effect on the height loss by the composite material with 3 % of volume fractions of ZnO NPs. Based on this it was concluded that PMMA/ZnO NPs composites showed improved in-vitro wear resistance compared to acrylic-resin denture teeth, so this new composite material should be preferred when occlusal stability is considered to be of high priority.",
publisher = "Inst Za Kovinske Materiale I In Tehnologie, Ljubjana",
journal = "Materiali in Tehnologije",
title = "Synthesis of PMMA/ZNO nanoparticles composite used for resin teeth",
volume = "51",
number = "5",
pages = "871-878",
doi = "10.17222/mit.2017.025"
}
Popović, D., Bobovnik, R., Bolka, S., Vukadinović, M., Lazić, V.,& Rudolf, R.. (2017). Synthesis of PMMA/ZNO nanoparticles composite used for resin teeth. in Materiali in Tehnologije
Inst Za Kovinske Materiale I In Tehnologie, Ljubjana., 51(5), 871-878.
https://doi.org/10.17222/mit.2017.025
Popović D, Bobovnik R, Bolka S, Vukadinović M, Lazić V, Rudolf R. Synthesis of PMMA/ZNO nanoparticles composite used for resin teeth. in Materiali in Tehnologije. 2017;51(5):871-878.
doi:10.17222/mit.2017.025 .
Popović, Danica, Bobovnik, Rajko, Bolka, Silvester, Vukadinović, Miroslav, Lazić, Vojkan, Rudolf, Rebeka, "Synthesis of PMMA/ZNO nanoparticles composite used for resin teeth" in Materiali in Tehnologije, 51, no. 5 (2017):871-878,
https://doi.org/10.17222/mit.2017.025 . .
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