Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion
Abstract
The aim of this study was to optimize the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide (Lucirin (R) TPO) in unfilled and filled composite resins in relation to the degree of conversion (DC). Increasing concentrations of Lucirin (R) TPO between 0.05-4.97 wt% were added to equimolar mixtures of Bis-GMA/TEGDMA. Filled resins contained 75 wt% fillers. Standardized samples were cured using a polywave LED light-curing unit (bluephase (R) G2, Ivoclar Vivadent). Increased initiator concentrations increased logarithmically the DC of unfilled and filled resins. The DC of unfilled resins was in the range of 73-91% at the top and 63-81% at the bottom surfaces and that of filled resins was in the range of 53-81% at the top and 47-70% at the bottom surfaces. The DC in unfilled and filled resins reached a plateau at 1.08 wt% and 1.50 wt% Lucirin (R) TPO, respectively. Fillers significantly reduced conversion but had no effect on the logarithmic relationship between initiator concent...ration and the DC.
Keywords:
Lucirin (R) TPO / Composite / Degree of conversion / Raman / Light curing unitSource:
Dental Materials Journal, 2012, 31, 5, 717-723Publisher:
- Japanese Soc Dental Materials Devices, Tokyo
Funding / projects:
- IADR Toshio Nakao Fellowship
- Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals (RS-172007)
DOI: 10.4012/dmj.2012-064
ISSN: 0287-4547
PubMed: 23037832
WoS: 000312429300002
Scopus: 2-s2.0-84867863395
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Institution/Community
Stomatološki fakultetTY - JOUR AU - Miletić, Vesna AU - Santini, Ario PY - 2012 UR - https://smile.stomf.bg.ac.rs/handle/123456789/1702 AB - The aim of this study was to optimize the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide (Lucirin (R) TPO) in unfilled and filled composite resins in relation to the degree of conversion (DC). Increasing concentrations of Lucirin (R) TPO between 0.05-4.97 wt% were added to equimolar mixtures of Bis-GMA/TEGDMA. Filled resins contained 75 wt% fillers. Standardized samples were cured using a polywave LED light-curing unit (bluephase (R) G2, Ivoclar Vivadent). Increased initiator concentrations increased logarithmically the DC of unfilled and filled resins. The DC of unfilled resins was in the range of 73-91% at the top and 63-81% at the bottom surfaces and that of filled resins was in the range of 53-81% at the top and 47-70% at the bottom surfaces. The DC in unfilled and filled resins reached a plateau at 1.08 wt% and 1.50 wt% Lucirin (R) TPO, respectively. Fillers significantly reduced conversion but had no effect on the logarithmic relationship between initiator concentration and the DC. PB - Japanese Soc Dental Materials Devices, Tokyo T2 - Dental Materials Journal T1 - Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion VL - 31 IS - 5 SP - 717 EP - 723 DO - 10.4012/dmj.2012-064 ER -
@article{ author = "Miletić, Vesna and Santini, Ario", year = "2012", abstract = "The aim of this study was to optimize the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide (Lucirin (R) TPO) in unfilled and filled composite resins in relation to the degree of conversion (DC). Increasing concentrations of Lucirin (R) TPO between 0.05-4.97 wt% were added to equimolar mixtures of Bis-GMA/TEGDMA. Filled resins contained 75 wt% fillers. Standardized samples were cured using a polywave LED light-curing unit (bluephase (R) G2, Ivoclar Vivadent). Increased initiator concentrations increased logarithmically the DC of unfilled and filled resins. The DC of unfilled resins was in the range of 73-91% at the top and 63-81% at the bottom surfaces and that of filled resins was in the range of 53-81% at the top and 47-70% at the bottom surfaces. The DC in unfilled and filled resins reached a plateau at 1.08 wt% and 1.50 wt% Lucirin (R) TPO, respectively. Fillers significantly reduced conversion but had no effect on the logarithmic relationship between initiator concentration and the DC.", publisher = "Japanese Soc Dental Materials Devices, Tokyo", journal = "Dental Materials Journal", title = "Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion", volume = "31", number = "5", pages = "717-723", doi = "10.4012/dmj.2012-064" }
Miletić, V.,& Santini, A.. (2012). Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion. in Dental Materials Journal Japanese Soc Dental Materials Devices, Tokyo., 31(5), 717-723. https://doi.org/10.4012/dmj.2012-064
Miletić V, Santini A. Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion. in Dental Materials Journal. 2012;31(5):717-723. doi:10.4012/dmj.2012-064 .
Miletić, Vesna, Santini, Ario, "Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion" in Dental Materials Journal, 31, no. 5 (2012):717-723, https://doi.org/10.4012/dmj.2012-064 . .