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Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion

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2012
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Authors
Miletić, Vesna
Santini, Ario
Article (Published version)
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Abstract
The aim of this study was to optimize the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide (Lucirin (R) TPO) in unfilled and filled composite resins in relation to the degree of conversion (DC). Increasing concentrations of Lucirin (R) TPO between 0.05-4.97 wt% were added to equimolar mixtures of Bis-GMA/TEGDMA. Filled resins contained 75 wt% fillers. Standardized samples were cured using a polywave LED light-curing unit (bluephase (R) G2, Ivoclar Vivadent). Increased initiator concentrations increased logarithmically the DC of unfilled and filled resins. The DC of unfilled resins was in the range of 73-91% at the top and 63-81% at the bottom surfaces and that of filled resins was in the range of 53-81% at the top and 47-70% at the bottom surfaces. The DC in unfilled and filled resins reached a plateau at 1.08 wt% and 1.50 wt% Lucirin (R) TPO, respectively. Fillers significantly reduced conversion but had no effect on the logarithmic relationship between initiator concent...ration and the DC.

Keywords:
Lucirin (R) TPO / Composite / Degree of conversion / Raman / Light curing unit
Source:
Dental Materials Journal, 2012, 31, 5, 717-723
Publisher:
  • Japanese Soc Dental Materials Devices, Tokyo
Funding / projects:
  • IADR Toshio Nakao Fellowship
  • Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals (RS-172007)

DOI: 10.4012/dmj.2012-064

ISSN: 0287-4547

PubMed: 23037832

WoS: 000312429300002

Scopus: 2-s2.0-84867863395
[ Google Scholar ]
21
18
URI
https://smile.stomf.bg.ac.rs/handle/123456789/1702
Collections
  • Radovi istraživača
Institution/Community
Stomatološki fakultet
TY  - JOUR
AU  - Miletić, Vesna
AU  - Santini, Ario
PY  - 2012
UR  - https://smile.stomf.bg.ac.rs/handle/123456789/1702
AB  - The aim of this study was to optimize the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide (Lucirin (R) TPO) in unfilled and filled composite resins in relation to the degree of conversion (DC). Increasing concentrations of Lucirin (R) TPO between 0.05-4.97 wt% were added to equimolar mixtures of Bis-GMA/TEGDMA. Filled resins contained 75 wt% fillers. Standardized samples were cured using a polywave LED light-curing unit (bluephase (R) G2, Ivoclar Vivadent). Increased initiator concentrations increased logarithmically the DC of unfilled and filled resins. The DC of unfilled resins was in the range of 73-91% at the top and 63-81% at the bottom surfaces and that of filled resins was in the range of 53-81% at the top and 47-70% at the bottom surfaces. The DC in unfilled and filled resins reached a plateau at 1.08 wt% and 1.50 wt% Lucirin (R) TPO, respectively. Fillers significantly reduced conversion but had no effect on the logarithmic relationship between initiator concentration and the DC.
PB  - Japanese Soc Dental Materials Devices, Tokyo
T2  - Dental Materials Journal
T1  - Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion
VL  - 31
IS  - 5
SP  - 717
EP  - 723
DO  - 10.4012/dmj.2012-064
ER  - 
@article{
author = "Miletić, Vesna and Santini, Ario",
year = "2012",
abstract = "The aim of this study was to optimize the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide (Lucirin (R) TPO) in unfilled and filled composite resins in relation to the degree of conversion (DC). Increasing concentrations of Lucirin (R) TPO between 0.05-4.97 wt% were added to equimolar mixtures of Bis-GMA/TEGDMA. Filled resins contained 75 wt% fillers. Standardized samples were cured using a polywave LED light-curing unit (bluephase (R) G2, Ivoclar Vivadent). Increased initiator concentrations increased logarithmically the DC of unfilled and filled resins. The DC of unfilled resins was in the range of 73-91% at the top and 63-81% at the bottom surfaces and that of filled resins was in the range of 53-81% at the top and 47-70% at the bottom surfaces. The DC in unfilled and filled resins reached a plateau at 1.08 wt% and 1.50 wt% Lucirin (R) TPO, respectively. Fillers significantly reduced conversion but had no effect on the logarithmic relationship between initiator concentration and the DC.",
publisher = "Japanese Soc Dental Materials Devices, Tokyo",
journal = "Dental Materials Journal",
title = "Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion",
volume = "31",
number = "5",
pages = "717-723",
doi = "10.4012/dmj.2012-064"
}
Miletić, V.,& Santini, A.. (2012). Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion. in Dental Materials Journal
Japanese Soc Dental Materials Devices, Tokyo., 31(5), 717-723.
https://doi.org/10.4012/dmj.2012-064
Miletić V, Santini A. Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion. in Dental Materials Journal. 2012;31(5):717-723.
doi:10.4012/dmj.2012-064 .
Miletić, Vesna, Santini, Ario, "Optimizing the concentration of 2,4,6-trimethylbenzoyldiphenylphosphine oxide initiator in composite resins in relation to monomer conversion" in Dental Materials Journal, 31, no. 5 (2012):717-723,
https://doi.org/10.4012/dmj.2012-064 . .

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